Halle Berry, Die Another Day
Berry's character, NSA agent Jinx Johnson, has a prominent role in 2002's Die Another Day. Jinx and Bond are romantically involved throughout the film, and she and Pierce Brosnan definitely had some intense chemistry. Berry has had a hugely popular acting career, appearing in everything from X-Men to The Call to John Wick.
Rosamund Pike, Die Another Day
Rosamund Pike plays M16 agent Miranda Frost in the 2002 film, Die Another Day. Since then, Pike starred in 2014's Gone Girl across from Ben Affleck and even received an Oscar nomination. She also starred in Pride & Prejudice, An Education, and Jack Reacher.