She's All That (1999)
High school itself is basically one big rom-com, so why not write about the high school experience? This film follows the school dork and the school jock as they navigate a budding relationship... Even though the jock started the relationship as a bet.
Eagle vs Shark (2007)
Taika Waititi was actually in a popular romantic comedy in New Zealand before his stint with Thor: Ragnarok. These two would definitely be classified as "misfits in love" as they navigate a relationship through their quirks. Watching them develop their relationship is amusing and sweet.